The deputy head of Westexe Technology college in Exeter has now resigned.
Beverely Maddern has been on sick leave for several weeks.
It follows an audit of the school's finances and management by devon County Council.
It was revealed that Mrs Maddern earned £85,000 as deputy head, and husband Steve £150,000 as the Head. He resigned last week.
Extra £3 million to help combat Devon’s winter road damage
Torbay will leave Blue Flag beaches scheme
Violence in schools 'more prevalent'
Hair raid thugs sought
Residents don't relish 24-hour maccies plan
